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Crystal growth, thermodynamical and structural study of CoGa2O4 and ZnCr2O4 single crystals

The growth of CoGa2O4 and ZnCr2O4 spinel single crystals by means of the chemical vapour transport technique using chlorine as a transport agent is reported here. A thermodynamical study of the CoGa2O4-Cl2 system has been performed in order to define the growth conditions, and structural investigations using X-ray diffraction are carried out. Moreover, the magnetic and electronic properties of the polycrystalline powdered samples were studied by means of magnetic susceptibility measurements, X-ray photoelectron spectroscopy and X-ray induced Auger spectroscopy.

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